Coverart for item
The Resource Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands

Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands

Label
Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Title
Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Creator
Subject
Language
eng
Member of
Cataloging source
MiAaPQ
Literary form
non fiction
Nature of contents
dictionaries
Series statement
Springer Theses Ser
Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Label
Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Link
http://libproxy.rpi.edu/login?url=https://ebookcentral.proquest.com/lib/rpi/detail.action?docID=4723615
Publication
Copyright
Related Contributor
Related Location
Related Agents
Related Authorities
Related Subjects
Related Items
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
  • Supervisor's Foreword -- Abstract -- Parts of this thesis have been published in the following journal articles:J. Hicks, E. Underhill, C. E. Kefalidis, L. Maron, C. Jones, A Mixed-Valence Tri-Zinc Complex, LZnZnZnL (L = Bulky Amide), Bearing a Linear Chain of Two-Coordinate Zinc Centres, Angew. Chem., Int. Ed., 2015, 54, 10000. Highlighted in Nature Chemistry, Chemistry in Australia and as a Hot Paper in Angew. Chem. Int. Ed.J. Hicks, C. Jones, Low-Coordinate Cobalt(I) Complexes Stabilized by an Extremely Bulky Amide Ligand, Organ -- Acknowledgements -- Declaration -- Contents -- Abbreviations -- Summary of Compounds -- 1 General Introduction -- 1.1 Transition Metals -- 1.2 Low Oxidation State Transition Metal Complexes -- 1.2.1 Bulky Ligands Used into Stabilise Low Oxidation State Complexes -- 1.2.2 Preparation of Low Oxidation State Transition Metal Complexes -- 1.3 Metal-Metal Bonding in Transition Metal Complexes -- 1.3.1 History -- 1.3.2 Quintuple Bonds -- 1.4 Magnesium(I) Complexes -- 1.4.1 Reactivity of Ý-Diketiminate Stabilised Magnesium(I) Complexes -- 1.4.2 Using Ý-Diketiminate Stabilised Magnesium(I) Complexes as Reducing Agents in Inorganic Synthesis -- References -- 2 Extremely Bulky Amido d-Block Metal(II) Halide Complexes -- 2.1 Introduction -- 2.1.1 Previously Reported Bulky Amido Transition Metal(II) Halide Complexes -- 2.1.2 Previously Reported Bulky Amido Group 12 Metal(II) Halide Complexes -- 2.1.3 Terphenyl Stabilised D-Block Metal Halide Complexes -- 2.1.3.1 Terphenyl Transition Metal(II) Halide Complexes -- 2.1.3.2 Terphenyl Group 12 Metal(II) Halide Complexes -- 2.1.4 Extremely Bulky Monodentate Amido Ligands -- 2.2 Research Outline -- 2.3 Results and Discussion -- 2.3.1 Preparation of Bulky Potassium Amide Salts -- 2.3.2 Bulky Amido First Row Transition Metal(II) Halide Complexes
  • 2.3.3 Bulky Amido Group 12 Metal(II) Halide Complexes -- 2.4 Conclusion -- 2.5 Experimental -- References -- 3 Preparation of Low Oxidation State Manganese Complexes Stabilised by Bulky Amide Ligands -- 3.1 Introduction -- 3.1.1 Low Oxidation State Manganese Complexes -- 3.1.1.1 Metal-Metal Bonded Manganese(I) Dimers -- 3.1.1.2 Carbonyl-free Manganese(I) Complexes Without Metal-Metal Bonds -- 3.2 Research Outline -- 3.3 Results and Discussion -- 3.3.1 Preparation and Characterisation of a Two-Coordinate Manganese(I) Dimer with an Unsupported Metal-Metal Bond -- 3.3.2 Preparation and Characterisation of a Two-Coordinate Manganese(0) Heterobimetallic Complex with an Unsupported Mn-Mg Bond -- 3.3.3 Reactivity of a Two-Coordinate Manganese(0) Heterobimetallic Complex -- 3.3.3.1 Reactivity of an Mn-Mg Bonded Complex Towards Inorganic Complexes -- 3.3.3.2 Reactivity of an Mn-Mg Bonded Complex Towards Small Organic Molecules and Gases -- 3.4 Conclusion -- 3.5 Experimental -- References -- 4 Preparation of Low Oxidation State Group 12 Metal Complexes Stabilised by Bulky Amide Ligands -- 4.1 Introduction -- 4.1.1 The First Molecular Compounds Possessing Group 12 Metal-Metal Bonds -- 4.1.2 Isolation of the First Zinc(I) Dimer -- 4.1.3 Other Metal-Metal Bonded Zinc(I) Compounds -- 4.1.3.1 A Homologous Series of Two-Coordinate Group 12 Metal-Metal Bonded Dimers -- 4.1.3.2 Other Recently Reported Low Oxidation State Group 12 Metal Complexes -- 4.2 Research Outline -- 4.3 Results and Discussion -- 4.3.1 Preparation and Characterisation of a Homologous Series of Group 12 Metal(I) Dimers -- 4.3.2 Preparation and Characterisation of a Two-Coordinate Zinc(0) Heterobimetallic Complex with an Unsupported Zn-Mg Bond -- 4.3.3 Attempts to Synthesise Two-Coordinate Cadmium(0) or Mercury(0) Heterobimetallic Complexes with Unsupported M-Mg Bonds
  • 4.3.4 Reactivity of a Two-Coordinate Zinc(0) Heterobimetallic Complex with an Unsupported Zn-Mg Bond -- 4.3.4.1 Preparation and Characterisation of a Homologous Series of Mixed-Valence Group 12 Metal Trimetallic Complexes -- 4.4 Conclusion -- 4.5 Experimental -- References -- 5 Preparation of Low Oxidation State Cobalt Complexes Stabilised by a Bulky Amide Ligand -- 5.1 Introduction -- 5.1.1 Low Oxidation State Cobalt Complexes Stabilised by Bulky Bidentate Monoanionic Ligands -- 5.1.2 Low Oxidation State Cobalt Complexes Stabilised by Bulky Monodentate Monoanionic Ligands -- 5.1.3 Other Relevant Low Coordinate, Low Oxidation State Cobalt Complexes -- 5.2 Research Outline -- 5.3 Results and Discussion -- 5.3.1 Preparation and Characterisation of Two Low Coordinate Amido Cobalt(I) Complexes -- 5.3.2 Reactivity of the Two Amido Cobalt(I) Complexes -- 5.4 Conclusion -- 5.5 Experimental -- References -- 6 Preparation of Molybdenum Aminogermylene and Aminogermylyne Complexes -- 6.1 Introduction -- 6.1.1 Previously Reported Transition Metal Tetrelyne Complexes -- 6.1.1.1 Transition Metal Germylyne Complexes -- 6.1.1.2 Transition Metal Stannylyne Complexes -- 6.1.1.3 Transition Metal Plumbylyne Complexes -- 6.1.1.4 Transition Metal-Silylyne Complexes -- 6.2 Research Outline -- 6.3 Results and Discussion -- 6.3.1 Preparation of Two Molybdenum Aminogermylene Complexes -- 6.3.2 Preparation of a Molybdenum Aminogermylyne Complex -- 6.4 Conclusion -- 6.5 Experimental -- References -- 7 Appendix -- 7.1 General Procedures -- 7.1.1 X-Ray Crystallography -- 7.1.2 Magnetic Susceptibility Measurements -- 7.1.3 EPR Spectroscopy Studies -- 7.1.4 Computational Studies -- 7.2 Miscellaneous Data -- 7.3 Summary of Crystallographic Data -- References
http://library.link/vocab/cover_art
https://contentcafe2.btol.com/ContentCafe/Jacket.aspx?Return=1&Type=S&Value=9789811029059&userID=ebsco-test&password=ebsco-test
Dimensions
unknown
http://library.link/vocab/discovery_link
{'f': 'http://opac.lib.rpi.edu/record=b4392833'}
Extent
1 online resource (214 pages)
Form of item
online
Isbn
9789811029059
Media category
computer
Media MARC source
rdamedia
Media type code
c
Sound
unknown sound
Specific material designation
remote

Library Locations

    • Folsom LibraryBorrow it
      110 8th St, Troy, NY, 12180, US
      42.729766 -73.682577
Processing Feedback ...