Coverart for item
The Resource Molecular Symmetry, Super-Rotation, and Semiclassical Motion : New Ideas for Solving Old Problems, by Hanno Schmiedt, (electronic resource)

Molecular Symmetry, Super-Rotation, and Semiclassical Motion : New Ideas for Solving Old Problems, by Hanno Schmiedt, (electronic resource)

Label
Molecular Symmetry, Super-Rotation, and Semiclassical Motion : New Ideas for Solving Old Problems
Title
Molecular Symmetry, Super-Rotation, and Semiclassical Motion
Title remainder
New Ideas for Solving Old Problems
Statement of responsibility
by Hanno Schmiedt
Creator
Contributor
Author
Subject
Language
eng
Summary
This book presents a range of fundamentally new approaches to solving problems involving traditional molecular models. Fundamental molecular symmetry is shown to open new avenues for describing molecular dynamics beyond standard perturbation techniques. Traditional concepts used to describe molecular dynamics are based on a few fundamental assumptions, the ball-and-stick picture of molecular structure and the respective perturbative treatment of different kinds of couplings between otherwise separate motions.  The book points out the conceptual limits of these models and, by focusing on the most essential idea of theoretical physics, namely symmetry, shows how to overcome those limits by introducing fundamentally new concepts. The book begins with an introduction to molecular symmetry in general, followed by a discussion of nuclear spin symmetry. Here, a new correlation between identical particle exchange and spin angular momentum symmetry of nuclei is exhibited. The central part of the book is the discussion of extremely floppy molecules, which are not describable in the framework of traditional theories. The book introduces a fundamentally new approach to describing the molecular dynamics of these molecules - the super-rotor model, which is based on a five-dimensional symmetry that has never been observed in molecules before. By applying the super-rotor theory to the prototype of floppy molecules, protonated methane, this model can consistently predict the symmetry and energy of low-energy states, which were characterized experimentally only a few years ago. The theoretical predictions agree with the experimental results, which makes the prospect of further developing the super-rotor theory and applying it to other molecules a promising one. In the final section, the book also covers the topic of ultrafast rotations, where usual quantum calculations reach their natural limits. A semi-classical method for determining rotational energies, developed in the early 1990s, is shown to be attachable to quantum calculations of the vibrational states. This new combined method is suitable for efficiently calculating ro-vibrational energies, even for molecular states with large angular momentum. 
Member of
Is part of
Image bit depth
0
Literary form
non fiction
Series statement
Springer Series on Atomic, Optical, and Plasma Physics,
Series volume
97
Molecular Symmetry, Super-Rotation, and Semiclassical Motion : New Ideas for Solving Old Problems, by Hanno Schmiedt, (electronic resource)
Label
Molecular Symmetry, Super-Rotation, and Semiclassical Motion : New Ideas for Solving Old Problems, by Hanno Schmiedt, (electronic resource)
Link
http://libproxy.rpi.edu/login?url=http://dx.doi.org/10.1007/978-3-319-66071-4
Publication
Related Contributor
Related Location
Related Agents
Related Authorities
Related Subjects
Related Items
Antecedent source
mixed
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
not applicable
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
New Ideas for Solving Old Problems - An Introduction -- Basic Concepts -- Schur-Weyl Duality in Molecules -- Reactive Collisions -- Introducing Extreme Floppiness -- Symmetry Beyond Perturbation Theory -- The Molecular Super-rotor
http://library.link/vocab/cover_art
https://contentcafe2.btol.com/ContentCafe/Jacket.aspx?Return=1&Type=S&Value=9783319660714&userID=ebsco-test&password=ebsco-test
Dimensions
unknown
http://library.link/vocab/discovery_link
{'f': 'http://opac.lib.rpi.edu/record=b4379962'}
Extent
IX, 171 p. 29 illus., 25 illus. in color.
File format
multiple file formats
Form of item
electronic
Isbn
9783319660714
Level of compression
uncompressed
Media category
computer
Media MARC source
rdamedia
Media type code
c
Other physical details
online resource.
Quality assurance targets
absent
Reformatting quality
access
Specific material designation
remote

Library Locations

    • Folsom LibraryBorrow it
      110 8th St, Troy, NY, 12180, US
      42.729766 -73.682577
Processing Feedback ...