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The Resource Dielectric Properties of Ionic Liquids

Dielectric Properties of Ionic Liquids

Label
Dielectric Properties of Ionic Liquids
Title
Dielectric Properties of Ionic Liquids
Creator
Subject
Language
eng
Member of
Cataloging source
MiAaPQ
Literary form
non fiction
Nature of contents
dictionaries
Series statement
Advances in Dielectrics Ser
Dielectric Properties of Ionic Liquids
Label
Dielectric Properties of Ionic Liquids
Link
http://libproxy.rpi.edu/login?url=https://ebookcentral.proquest.com/lib/rpi/detail.action?docID=4619894
Publication
Copyright
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Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
multicolored
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
  • Preface -- Contents -- 1 Introduction to Ionic Liquids -- Abstract -- 1.1 Synthetic Ways to Ionic Liquids as Source for Possible Impurities -- 1.2 Liquid Range of Ionic Liquids -- 1.3 Viscosity of Ionic Liquids -- 1.4 Density of Ionic Liquids -- 1.5 Polarity of Ionic Liquids -- 1.6 New Polymer Materials Derived from Ionic Liquids -- References -- 2 Rotational and Translational Diffusion in Ionic Liquids -- Abstract -- 2.1 Introduction -- 2.2 Experimental Details -- 2.3 Results and Discussion -- 2.3.1 Charge Transport and Dynamic Glass Transition in Ionic Liquids -- 2.3.2 Elucidating the Correlation Between Characteristic Hopping Lengths and Molecular Volumes of Ionic Liquids -- 2.4 Conclusions -- Acknowledgments -- References -- 3 Femto- to Nanosecond Dynamics in Ionic Liquids: From Single Molecules to Collective Motions -- Abstract -- 3.1 Introduction -- 3.2 Broadband Dielectric Spectra of Ionic Liquids -- 3.3 Translation or Rotation-Comparison to Computational Results -- 3.4 Local Versus Global Dielectric Response-Comparison to Solvation Response -- 3.5 Balanced Sensitivities-Comparison to Optical Kerr Effect Spectroscopy -- 3.6 Adding Molecular Specificity-Comparison to Ultrafast Infrared Spectroscopy -- 3.7 Conclusions -- Acknowledgments -- References -- 4 High-Pressure Dielectric Spectroscopy for Studying the Charge Transfer in Ionic Liquids and Solids -- Abstract -- 4.1 Conductivity Measurements Under High-Pressure Conditions. How to Exert Pressure on the Sample? -- 4.2 Pressure Sensitivity of Ion Dynamics. How Much Pressure Do We Need to "Supercool" Ionic System? -- 4.3 Thermal and Density Fluctuations to the Temperature Dependence of vdc at Ambient and Elevated Pressure -- 4.4 Density Scaling of Ionic Systems -- 4.5 Relation Between Ion Dynamics and Structural Relaxation at Ambient and Elevated Pressure
  • 4.5.1 Are the Stockes-Einstein and Walden Laws Always Satisfied? -- 4.5.2 How to Quantify Decoupling Between the Charge Transfer and Structural/Segmental Relaxation in Ionic Conductors? -- 4.5.3 How to Control the Time Scale Separation Between Charge and Mass Diffusion? -- 4.6 Conclusions and Perspectives -- Acknowledgement -- References -- 5 Glassy Dynamics and Charge Transport in Polymeric Ionic Liquids -- Abstract -- 5.1 Introduction -- 5.2 Experimental Details -- 5.3 Results and Discussion -- 5.4 Conclusion -- Acknowledgments -- References -- 6 Ionic Transport and Dielectric Relaxation in Polymer Electrolytes -- Abstract -- 6.1 Introduction -- 6.2 Dielectric Relaxation in Polymer Electrolytes -- 6.2.1 Analysis of Dielectric Spectra of Polymer Electrolytes -- 6.2.1.1 Spectrum Analysis Protocols -- 6.2.1.2 Analysis of Electrode Polarization: Ion Number Density and Diffusivity -- 6.2.2 Low Salt Concentration: Emergence of Ionic Mode -- 6.2.2.1 Pressure Dependence of the Ionic Mode -- 6.2.2.2 Slow Segmental Relaxation -- 6.2.2.3 Nature of the Ionic Mode -- 6.2.3 Emergence of Additional Relaxation Modes at Higher Salt Concentrations -- 6.3 Ionic Transport in Polymer Electrolytes -- 6.3.1 Theory of Ionic Mobility in Electrolyte Solutions -- 6.3.2 Models of Ionic Transport in Polymer Electrolytes -- 6.3.2.1 Free-Volume Model -- 6.3.2.2 Dynamic Bond Percolation Model -- 6.3.3 Coupling and Decoupling Between Conductivity and Polymer Relaxation -- 6.3.3.1 Observation of Decoupling in Polymer Electrolytes -- 6.3.3.2 Walden Plot Analysis -- 6.4 Summary -- Acknowledgments -- References -- 7 Electrochemical Double Layers in Ionic Liquids Investigated by Broadband Impedance Spectroscopy and Other Complementary Experimental Techniques -- Abstract -- 7.1 Broadband Impedance Spectroscopy -- 7.1.1 Introduction -- 7.1.2 Theory of Impedance Spectroscopy
  • 7.1.3 Practical EIS Pitfalls -- 7.1.3.1 Cell Design for Three-Electrode Measurements -- 7.1.3.2 Non-stationary Electrochemical Systems -- 7.1.3.3 Fitting Algorithms -- 7.1.4 Application to Metal
  • 9.2 Heat Capacity Spectroscopy -- 9.3 Results -- 9.3.1 [C6MIm][NTf2] -- 9.3.2 [C4MIm][NTf2] -- 9.3.3 [C8MIm][NTf2] -- 9.4 Summary -- Acknowledgment -- References -- Index
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{'f': 'http://opac.lib.rpi.edu/record=b4385789'}
Extent
1 online resource (241 pages)
Form of item
online
Isbn
9783319324890
Media category
computer
Media MARC source
rdamedia
Media type code
c
Sound
unknown sound
Specific material designation
remote

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