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The Resource Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene, by Ruijun Hou, (electronic resource)

Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene, by Ruijun Hou, (electronic resource)

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Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
Title
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
Statement of responsibility
by Ruijun Hou
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Author
Subject
Language
eng
Summary
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd{u2013}Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
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0
Literary form
non fiction
Series statement
Springer Theses, Recognizing Outstanding Ph.D. Research,
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene, by Ruijun Hou, (electronic resource)
Label
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene, by Ruijun Hou, (electronic resource)
Link
http://libproxy.rpi.edu/login?url=http://dx.doi.org/10.1007/978-981-10-0773-6
Publication
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Antecedent source
mixed
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
not applicable
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
Introduction -- Experimental and Theoretical Methods -- Design of Pd-Ni Bimetallic Catalyst -- Effect of Oxide Supports on Pd{u2013}Ni Bimetallic Catalysts -- Replacing Precious Metals with Carbide Catalysts -- Liquid Phase Hydrogenation of Acetylene -- Conclusion
http://library.link/vocab/cover_art
https://contentcafe2.btol.com/ContentCafe/Jacket.aspx?Return=1&Type=S&Value=9789811007736&userID=ebsco-test&password=ebsco-test
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unknown
http://library.link/vocab/discovery_link
{'f': 'http://opac.lib.rpi.edu/record=b4258547'}
Extent
XII, 141 p. 83 illus., 42 illus. in color.
File format
multiple file formats
Form of item
electronic
Isbn
9789811007736
Level of compression
uncompressed
Media category
computer
Media MARC source
rdamedia
Media type code
c
Other physical details
online resource.
Quality assurance targets
absent
Reformatting quality
access
Specific material designation
remote

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